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| Special | Eerste uitzending |
|---|---|
| S00E01 - Promo Premieres November 1st! | 25/10/2012 |
| S00E02 - KRISTEN SCHAAL & JOHN HODGMAN Astronaut Session | 01/11/2012 |
| S00E03 - The Science of Video Games | 08/11/2012 |
| S00E04 - The Science of the Mind | 15/11/2012 |
| S00E05 - ALAN RICKMAN joins StarTalk | 29/11/2012 |
| S00E06 - WIL WHEATON & Science of Star Trek | 06/12/2012 |
| S00E07 - WU-TANG's GZA raps and rhymes | 13/12/2012 |
| S00E09 - CHRIS HARDWICK & BABA BOOEY at SDCC | 03/01/2013 |
| S00E10 - ANTHONY BOURDAIN dishes on Food | 10/01/2013 |
| S00E11 - Jim Gaffigan & Sarah Silverman: Curiosity Mars Rover | 17/01/2013 |
| S00E12 - Dr.Ruth The Science of Sex | 05/02/2013 |